what are centrosymmetric complexes and Laporte rule. kindly explain.
aakansha , 8 Years ago
Grade 12th pass
AIPMT> what are centrosymmetric complexes and La...
1 Answers
Umakant biswal
Last Activity: 8 Years ago
dear aakansha
the molecule which have an inversion center called as centrosymmetric complex .
and laporte rule only applies to the centrosymmetric complexes due to its nature and propoerty .
The Laporte rule is a spectroscopic selection rule that only applies to centrosymmetric molecules (those with an inversion centre) and atoms. ... Allowed transitions in such molecules must involve a change in parity, either g → u or u → g.
so, for that reason , the d-d transition forbidden for some molecule
hope it clears
regards
the molecule which have an inversion center called as centrosymmetric complex .
and laporte rule only applies to the centrosymmetric complexes due to its nature and propoerty .
The Laporte rule is a spectroscopic selection rule that only applies to centrosymmetric molecules (those with an inversion centre) and atoms. ... Allowed transitions in such molecules must involve a change in parity, either g → u or u → g.
so, for that reason , the d-d transition forbidden for some molecule
hope it clears
regards
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