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How to find the molecular electronic configuration of heteroatomic molecules like CN- NO-, NO+, KO2, etc? Is this strictly valid for heteroatomic molecules? Please explain.

How to find the molecular electronic configuration of heteroatomic molecules like CN- NO-, NO+, KO2, etc? 
Is this strictly valid for heteroatomic molecules?
Please explain.

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2 Answers

Arun
25750 Points
5 years ago
Dear student
 
You can use Molecular orbital diagrams for the same.
Hope it helps
 
Regards
Arun (askIITians forum expert)
Abhijeet kumar
26 Points
5 years ago
Molecular orbital theory for hetroatomic molecules is slightly different from homoatomic molecules. In homoatomic molecules both atoms are of same atoms so there energy is also same but in hetroatomic molecules energy of different atoms is different .Atoms having lower atomic mass have high energy . However MOT is basically used to calculate bond order . For above given molecules the result is same if we solve it as homoatomic or hetroatomic but it is different for carbon monoxide 

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