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aniline does not give fridalcraft reaction, why?

aniline does not give fridalcraft reaction, why?

Grade:12th Pass

3 Answers

Anirban nayak
14 Points
9 years ago

amine group present in aniline undergoes lewis acid base reaction with catalyst aluminium chloride.so there is no more aluminium chloride left for reaction to take place . however if aluminium chloride is taken in excess , some meta isomer is produced.

Sarthak Chaturvedi
18 Points
9 years ago

This is because in presence of AlCl3, reaction occurs between NH2 group of aniline & AlCl3.

NARENDER
19 Points
4 years ago
Because of NH2 has Lewis Base character then aniline reacts with Lewis acid AlCl3 and inhibit the synthesis of electrophile Which is necessary to attack on benzene ring

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