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The extent to which hydrolysis proceeds is expressed as the degree of hydrolysisand is defined as the fraction of one mole of the salt that is hydrolysed when the equilibrium has been attained. It is generally expressed as h or x.
h = (Amount of salt hydrolysed)/(Total salt taken)
Considering again eq. (i),
Kh = x2C/(1-x) or Kh = h2C/(1-h)
When h is very small (1-h) → 1,
H2 = Kh × 1/c
or h = √(Kh/C) = √(Kw/Kb C)
[H+] = h × C = √(C Kh)/Kb
log [H+] = 1/2 log Kw + 1 1/2log C - 1/2log Kb
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