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Grade Upto college level Physical Chemistry

write chemical tests to distinguish between the following pairs of compounds: (i) Propanal and propanone (ii) Methyl acetate and ethyl acetate.

Profile image of Manvendra Singh chahar
12 Years agoGrade Upto college level
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1 Answer

Profile image of Gaurav
11 Years ago
Hello student

(i)Propanal and propanone :
On adding NaOH+I2 ,propanone gives yellowppt of Iodoform whereas propanal does not.
(ii) Methyl acetate and ethyl acetate: Ethyl acetate on hydrolysis gives ethanol
which forms yellow ppt of Iodoform on adding NaOH+I2. Methylacetate on
hydrolysis gives methanol which does not give Iodoform reaction.