Mukesh Sharma
Last Activity: 11 Years ago
The regular decrease (contraction) in the size of the atoms and ions
with increasing atomic number is known as lanthanide contraction.
Lanthanoid Contraction: The
steady decrease in the atomic and ionic radii of the transition metals
as the atomic number increases. This is because of filling of 4f
orbitals before the 5d orbitals. This contraction is size is quite
regular. This is called lanthanoid contraction. It is because of
lanthanoid contraction that the atomic radii of the second row of
transition elements are almost similar to those of the third row of
transition elements.
Thus, the regular decrease (contraction) in
the size of the atoms and ions with increasing atomic number is known as
lanthanide contraction.
Actinoid Contraction: The gradual decrease in the ionic radii with the increase in atomic no. is called actinoid contraction.
Explanation:
It is due to the imperfect shielding of one 5f electrons by another in
the same subshell. Along the series, the nuclear charge and no. of 5f
electrons increases by one unit. however, due to imperfect shielding of
5f orbitals, the effective nuclear charge increases which results in
contraction of the size.
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Mukesh Sharma
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