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The overall rate of a reaction (the one which you would measure if you did some experiments) is controlled by the rate of the slowest step. In the example above, the hydroxide ion can't combine with the positive ion until that positive ion has been formed. The second step is in a sense waiting around for the first slow step to happen.
The slow step of a reaction is known as the rate determining step.
As long as there is a lot of difference between the rates of the various steps, when you measure the rate of a reaction, you are actually measuring the rate of the rate determining step.
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