Initially:
100g sample of H2o(liquid)
Density=Mass/volume
Volume=Mass/density
Mass=100/1000=0.1
Density= 1000
So, volume=0.1/1000=10-4
Now,
60g gas + 40g water
Volume=V1+V2=M1/D1 +M2+D2
=(60/1000)/0.6 +(40/1000)/1000
=10-1+4×10-5
Work done=P(∆V)
=1×(V2-V1)
=(10-1+4×10-5)-(10-4)
=0.09994
=0.09994×1000 Liter-atm/K mole
=99.94×100 joule/K mole
=9994 J/K mol