Flag Physical Chemistry> S orbital...
question mark

why the shape of s orbital is sperical and that of p dumbell.give specific reason

Artist Ali , 14 Years ago
Grade 12
anser 1 Answers
SAGAR SINGH - IIT DELHI

Last Activity: 14 Years ago

Dear student,

All s orbitals are spherical in shape and have spherical symmetry. This means that the wave function will depend only on the distance from the nucleus and not on the direction.

In any atom, the size of the s orbital increases as the principal quantum number of the orbital increases but the geometry remains spherical. The electron density also tends to extend further. Other orbitals behave in the same way as the principal quantum numbers of the orbitals increase.

Orbitals with subshell quantum number l = 1 are called p orbitals. Since the magnetic quantum number m can be -1, 0, or +1 when the value of the subshell quantum number l is one, p orbitals come in sets of three. In each set, one of the orbitals is aligned along each of the three mutually perpendicular axes of the atom; these axes are traditionally designated x, y, and z. The three 2p orbitals are correspondingly designated 2px, 2py, and 2pz. The p orbitals either as a set or individually do not have spherical symmetry and so a simple plot of radial probability density cannot be made for them. If, however, the distance from the nucleus is taken along any one of the three axes and the orbital is that along the same axis, then a suitable plot can be made.

 

Please feel free to ask your queries here. We are all IITians and here to help you in your IIT JEE preparation.

All the best.

Win exciting gifts by answering the questions on Discussion Forum. So help discuss any query on askiitians forum and become an Elite Expert League askiitian.

Now you score 5+15 POINTS by uploading your Pic and Downloading the Askiitians Toolbar  respectively : Click here to download the toolbar..

 

Askiitians Expert

Sagar Singh

B.Tech, IIT Delhi

Provide a better Answer & Earn Cool Goodies

star
LIVE ONLINE CLASSES

Prepraring for the competition made easy just by live online class.

tv

Full Live Access

material

Study Material

removal

Live Doubts Solving

assignment

Daily Class Assignments


Ask a Doubt

Get your questions answered by the expert for free