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When 1-pentyne (A) is treated with 4N alcoholic KOH at 175°C, it is converted slowly into an equillibrium mixture of 1.3% 1-pentyne (A), 9.5% 2-pentyne (B) and 3.5% of 1.2-pentadiene (C) .The equillibrium was maintained at 175°C. Calculate ΔG° for the following eqilibria.
B ↔ A, ΔG°1=??
B ↔ C, ΔG°2=??
From the calculated value of ΔG°1 & ΔG°2 indicate the order of stabiity of (A), (B), & (C). Write a reasonable reaction mechanism showing al intermediates leading to (A), (B) & (C).
Dear student,
Gibbs Free Energy (G) - The energy associated with a chemical reaction that can be used to do work. The free energy of a system is the sum of its enthalpy (H) plus the product of the temperature (Kelvin) and the entropy (S) of the system:
Free energy of reaction (G)
Standard-state free energy of reaction (G)
Standard-state conditions
Measurements are also generally taken at a temperature of 25C (298 K)
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