Flag Organic Chemistry> What is the difference between dsp 2 and ...
question mark

What is the difference between dsp2 and sp3d? Please explain with proper reason

Indranil Roy , 11 Years ago
Grade 11
anser 1 Answers
Aarti Gupta

Last Activity: 11 Years ago

Hybridisation is of various types depending on the types of orbitals involved.dsp2 and sp3d are also the type of hybridisation.In dsp2,inner d-orbitals participates and in sp3d outer d-orbital participates.
For ex- in [Ni(CN)4]2-In nickel the configuration will be 3d8,4s2,4p0.But in the complex it is in +2 oxidation state thus configuration becomes 3d8,4s0,4p0.When dsp2 hybridisation occurs one of the 3d orbital gets vacant by shifting its e- to the previous d-orbital thereby one 3d,one 4s and one of the 4p orbital gets hybridised forming four dsp2 hybrid orbitals.Now each of these orbitals receives a pair of electrons from cyanide ion,and the geometry will be square planar.Thus inner 3d-orbital is participating in the hybridisation so it will be dsp2 hybridisation.
Now in sp3d type of hybridisation the difference is that the outer d-orbital i.e 4d -orbital will involved not inner 3d ,thereby forming five-hybrid orbitals and the geometry will be trigonal bipyramidal.
star
LIVE ONLINE CLASSES

Prepraring for the competition made easy just by live online class.

tv

Full Live Access

material

Study Material

removal

Live Doubts Solving

assignment

Daily Class Assignments