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Grade: 12th pass
        
Please explain why the reaction of neopentane yields 1- chloro- 2,2-dimethyl propane when treated with chlorine molecule during free radical mechanism ?
why not 1,2 methyl shift to give more stable tertiary free radical as compared to less stable primary free radicle????
please reply.
3 years ago

Answers : (6)

grenade
2056 Points
							
because for 1,2 me shift carbocation is necessary
free radical cannt be shifted mind it
3 years ago
ng29
1698 Points
							
in this type of reaction free carbocation is not formed
and for any shift carbocation is necessary , so no shift occurs
u can refer sn sanyal for reactions and mechanisms
 
APPROVE IF USEFUL
3 years ago
Ishtiyak Qadir
35 Points
							

but in this reaction 1,2 shift of phenyl group is observed

3 years ago
grenade
2056 Points
							
here phenyl gp is observed because of its mesomeric capcity
u asked for methyl
3 years ago
grenade
2056 Points
							
ant this particular case is still unclear acc to wiki
3 years ago
grenade
2056 Points
							
@ng29 its all about wiki
3 years ago
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