which is more stable and why ? plz explain.
(CD3)3C+ OR (CH3)3C+
which is more stable and why ? plz explain.
(CD3)3C+ OR (CH3)3C+
tandrila das , 16 Years ago
Grade Upto college level
Organic Chemistry> stability...
1 Answers
Askiitians Expert Himanshu Geed - IIT Delhi
Dear Tandrila,
Books like Morrison Boyd have shown that breaking a C-D bond is 7 times tougher than breaking a C-H bond. These are experimental results.
The stability of the carbocation depends on the hyperconjugation effect in both the compounds. Since, it's harder for (CD3)3C+ to show hyperconjugation than (CH3)3C+ . So the second compound will be more stable than the first one.
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