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mechanism of electrophilip substances give reactions plz
EXPLAINING THE REACTION BETWEEN SYMMETRICAL ALKENES AND SULPHURIC ACID This page guides you through the mechanism for the electrophilic addition of sulphuric acid to symmetrical alkenes like ethene or cyclohexene. Unsymmetrical alkenes are covered separately, and you will find a link at the bottom of the page. The electrophilic addition reaction between ethene and sulphuric acid This reaction looks more complicated than the reaction between ethene and hydrogen bromide, but it isn''t! The only problem is that H2SO4 is a more complicated structure than HBr. The mechanisms are exactly the same.
The structure of sulphuric acid Compare the structure of sulphuric acid with that of hydrogen bromide:
The structure of ethene is shown in the diagram on the right. The pi bond is an orbital above and below the plane of the rest of the molecule, and relatively exposed to things around it. The two electrons in this orbital are highly attractive to anything which is positively charged. Note: If you aren''t sure about this, it would be a good idea to read the introductory page on electrophilic addition before you go on. Use the BACK button on your browser to return to this page. The slightly positive hydrogen atom in the sulphuric acid acts as an electrophile, and is strongly attracted to the electrons in the pi bond. The electrons from the pi bond move down towards the slightly positive hydrogen atom. In the process, the electrons in the hydrogen-oxygen bond are repelled down until they are entirely on the oxygen atom, producing a negative ion. So the first stage of the reaction is: Help! If you aren''t sure about the use of curly arrows in mechanisms, you must follow this link before you go on. Use the BACK button on your browser to return to this page. The ion with a positive charge on the carbon atom is called a carbocation or carbonium ion (an older term). Why is there a positive charge on the carbon atom? The pi bond was originally made up of an electron from each of the carbon atoms. Both of those electrons have been used to make a new bond to the hydrogen. That leaves the right-hand carbon an electron short - hence positively charged. In the second stage of the mechanism, the lone pair of electrons on the oxygen atom is strongly attracted to the positive carbon and moves towards it until a bond is formed. Note: There are other lone pairs around the oxygen atom as well, but we are only showing one of them for clarity. The overall mechanism is therefore The electrophilic addition reaction between cyclohexene and sulphuric acid Once again * the pi bond breaks and the pair of electrons is used to form a bond with the hydrogen atom; * the electrons in the hydrogen-oxygen bond are pushed on to the oxygen atom giving it a full negative charge; * the lower carbon atom in the original C=C bond becomes positively charged because the electron it originally supplied to the pi bond has been moved away to form the new bond. Note: Be prepared to draw the sulphuric acid various ways around (on its side, upside-down, etc) so that it fits more tidily into the mechanism you are writing. Also: Be careful to attach the hydrogen to the correct carbon atom. As the curly arrow has been drawn, you can think of the electron pair pivotting around the top carbon atom. The electrons stay attached to that carbon, and so that''s the one the hydrogen must join on to. In the second stage, the lone pair on the negatively charged oxygen is attracted towards the positively charge carbon and forms a bond with it. The overall mechanism is therefore
EXPLAINING THE REACTION BETWEEN SYMMETRICAL ALKENES AND SULPHURIC ACID This page guides you through the mechanism for the electrophilic addition of sulphuric acid to symmetrical alkenes like ethene or cyclohexene. Unsymmetrical alkenes are covered separately, and you will find a link at the bottom of the page. The electrophilic addition reaction between ethene and sulphuric acid This reaction looks more complicated than the reaction between ethene and hydrogen bromide, but it isn''''t! The only problem is that H2SO4 is a more complicated structure than HBr. The mechanisms are exactly the same. The structure of sulphuric acid Compare the structure of sulphuric acid with that of hydrogen bromide: The structure of ethene is shown in the diagram on the right. The pi bond is an orbital above and below the plane of the rest of the molecule, and relatively exposed to things around it. The two electrons in this orbital are highly attractive to anything which is positively charged. Note: If you aren''''t sure about this, it would be a good idea to read the introductory page on electrophilic addition before you go on. Use the BACK button on your browser to return to this page. The slightly positive hydrogen atom in the sulphuric acid acts as an electrophile, and is strongly attracted to the electrons in the pi bond. The electrons from the pi bond move down towards the slightly positive hydrogen atom. In the process, the electrons in the hydrogen-oxygen bond are repelled down until they are entirely on the oxygen atom, producing a negative ion. So the first stage of the reaction is: Help! If you aren''''t sure about the use of curly arrows in mechanisms, you must follow this link before you go on. Use the BACK button on your browser to return to this page. The ion with a positive charge on the carbon atom is called a carbocation or carbonium ion (an older term). Why is there a positive charge on the carbon atom? The pi bond was originally made up of an electron from each of the carbon atoms. Both of those electrons have been used to make a new bond to the hydrogen. That leaves the right-hand carbon an electron short - hence positively charged. In the second stage of the mechanism, the lone pair of electrons on the oxygen atom is strongly attracted to the positive carbon and moves towards it until a bond is formed. Note: There are other lone pairs around the oxygen atom as well, but we are only showing one of them for clarity. The overall mechanism is therefore The electrophilic addition reaction between cyclohexene and sulphuric acid Once again * the pi bond breaks and the pair of electrons is used to form a bond with the hydrogen atom; * the electrons in the hydrogen-oxygen bond are pushed on to the oxygen atom giving it a full negative charge; * the lower carbon atom in the original C=C bond becomes positively charged because the electron it originally supplied to the pi bond has been moved away to form the new bond. Note: Be prepared to draw the sulphuric acid various ways around (on its side, upside-down, etc) so that it fits more tidily into the mechanism you are writing. Also: Be careful to attach the hydrogen to the correct carbon atom. As the curly arrow has been drawn, you can think of the electron pair pivotting around the top carbon atom. The electrons stay attached to that carbon, and so that''''s the one the hydrogen must join on to. In the second stage, the lone pair on the negatively charged oxygen is attracted towards the positively charge carbon and forms a bond with it. The overall mechanism is therefore
EXPLAINING THE REACTION BETWEEN SYMMETRICAL ALKENES AND SULPHURIC ACID This page guides you through the mechanism for the electrophilic addition of sulphuric acid to symmetrical alkenes like ethene or cyclohexene. Unsymmetrical alkenes are covered separately, and you will find a link at the bottom of the page. The electrophilic addition reaction between ethene and sulphuric acid This reaction looks more complicated than the reaction between ethene and hydrogen bromide, but it isn''''t! The only problem is that H2SO4 is a more complicated structure than HBr. The mechanisms are exactly the same.
The structure of ethene is shown in the diagram on the right. The pi bond is an orbital above and below the plane of the rest of the molecule, and relatively exposed to things around it. The two electrons in this orbital are highly attractive to anything which is positively charged. Note: If you aren''''t sure about this, it would be a good idea to read the introductory page on electrophilic addition before you go on. Use the BACK button on your browser to return to this page. The slightly positive hydrogen atom in the sulphuric acid acts as an electrophile, and is strongly attracted to the electrons in the pi bond. The electrons from the pi bond move down towards the slightly positive hydrogen atom. In the process, the electrons in the hydrogen-oxygen bond are repelled down until they are entirely on the oxygen atom, producing a negative ion. So the first stage of the reaction is: Help! If you aren''''t sure about the use of curly arrows in mechanisms, you must follow this link before you go on. Use the BACK button on your browser to return to this page. The ion with a positive charge on the carbon atom is called a carbocation or carbonium ion (an older term). Why is there a positive charge on the carbon atom? The pi bond was originally made up of an electron from each of the carbon atoms. Both of those electrons have been used to make a new bond to the hydrogen. That leaves the right-hand carbon an electron short - hence positively charged. In the second stage of the mechanism, the lone pair of electrons on the oxygen atom is strongly attracted to the positive carbon and moves towards it until a bond is formed. Note: There are other lone pairs around the oxygen atom as well, but we are only showing one of them for clarity. The overall mechanism is therefore The electrophilic addition reaction between cyclohexene and sulphuric acid Once again * the pi bond breaks and the pair of electrons is used to form a bond with the hydrogen atom; * the electrons in the hydrogen-oxygen bond are pushed on to the oxygen atom giving it a full negative charge; * the lower carbon atom in the original C=C bond becomes positively charged because the electron it originally supplied to the pi bond has been moved away to form the new bond. Note: Be prepared to draw the sulphuric acid various ways around (on its side, upside-down, etc) so that it fits more tidily into the mechanism you are writing. Also: Be careful to attach the hydrogen to the correct carbon atom. As the curly arrow has been drawn, you can think of the electron pair pivotting around the top carbon atom. The electrons stay attached to that carbon, and so that''''s the one the hydrogen must join on to. In the second stage, the lone pair on the negatively charged oxygen is attracted towards the positively charge carbon and forms a bond with it. The overall mechanism is therefore
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