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Grade 12Organic Chemistry

can anyone pls tell me for what conditions will the product be an alkene and for what will it be an ether-

C2H5OH + Al2O3 --->

Profile image of Amol dave
15 Years agoGrade 12
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4 Answers

Profile image of Ritvik Gautam
ApprovedApproved Tutor Answer15 Years ago

At higher temperatures, elimination takes place, hence an alkene will be formed.

While at lower temperatures, substitution takes place, hence an ether will be formed.

 

 

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Profile image of Jaya IITK
ApprovedApproved Tutor Answer15 Years ago

temp above 343 gives alkene and below ether

 

BEST OF LUCK!!!!!!!!!!!!!!!!

 

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Profile image of Godfrey Classic Prince
ApprovedApproved Tutor Answer15 Years ago

Dear Amol dave,

This is a simple way of making gaseous alkenes like ethene. If ethanol vapour is passed over heated aluminium oxide powder, the ethanol is essentially cracked to give ethene and water vapour.

For getting an Ether from Ethanol,use two moles of Ethanol with the Oxidising agent Al2O3 at 413 K gives Ethoxyethane !

         2 CH3-CH2-OH  ----------> CH3-CH2-O-CH2-CH3 + H2O

 

Hope you understood !

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Profile image of Ashwin Sinha
15 Years ago

Dear Amol Dave,

 Temp. > 343 K will give alkene, & temp. lower than this will give ether!!!!!

 

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