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Dear Jauneet Singh,
Let the force due to buoyancy be B.
In the first case the equation will be
Mg - B = Ms
In the second case the equation will be
B - (M-m)g = (M-m)s
Since the volume is unchanged, the force of Buoyancy remains unchanged as same amount of air is displaced even now and the new mass is (M-m)
Adding the two equations we get,
mg = (2M-m)s
or m(g+s)=2Ms
or m=2Ms/(g+s)
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