Umakant biswal
Last Activity: 8 Years ago
@ kirti
in Nicl4 the central atom ni , whoose valence shell configuration in free state is 3d8,4s0, 4p0 .
as cl are weak ligand , and arrengement of eight 3d electron in ni 2+ ion and in (nicl4)2-
ion will remain same . thus , it have SP3 hybridisation which have tetradehdral geometry . and are paramagnetic in nature ,
while in the case of (PDCL4) 2- IT WILL BE dsp2 hybridisation , and the structure is
square bipyramidal .
HOPE IT CLEARS YOUR DOUBT
ALL THE BEST ..