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In CuSO4.5H2O, four water molecules are coordinated to Cu+2, while one is hydrogen bonded with SO42-.
Copper sulfate pentahydrate contains copper(II) in a geometry best described as distorted octahedral. The copper(II) is bound to four water molecules in a square-planar geometry and two oxygen atoms from two sulfate ions (one H2O is H-Bonded here).
This salt dissolves in water to produce the pale-blue [Cu(H2O)6]2+ ion, in which two of the water molecules are less tightly held and have longer bond distances.
according through werners theory one of thye five molecules of H2omolecules will attach to the So4 molecules in the form of hydrozen bonding. it will act as both primary and secondary molecule so co-ordination number will be 4
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