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give one chemical test to distinguish between the following pair of compound methylamine and N,N-dimethylamine

give one chemical test to distinguish between the following pair of compound
methylamine and N,N-dimethylamine

Grade:12

1 Answers

Arun
25750 Points
5 years ago

Methylamine and dimethylamine can be distinguished by the carbylamine test.

 
Carbylamine test: Aliphatic and aromatic primary amines on heating with chloroform and ethanolic potassium hydroxide form foul-smelling isocyanides or carbylamines. Methylamine (being an aliphatic primary amine) gives a positive carbylamine test, but dimethylamine does not.

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