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PARESH NAYYAR Grade:
        

which is more acidic 


A)ortho nitro phenol


B)para nitro phenol

6 years ago

Answers : (2)

AKASH GOYAL AskiitiansExpert-IITD
419 Points
										

Dear paresh


Because in the ortho-isomer the proton on the -OH group can hydrogen-bond with one of the oxygen atoms of the -NO2 group, making it harder to lose the proton.
With the para-isomer this can't happen


hence para nitro phenol is more acidic


All the best.


AKASH GOYAL


AskiitiansExpert-IITD


 


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6 years ago
vikas askiitian expert
510 Points
										

para nitro phenol is  more acidic because in orthonitro phenol there is intramolecular


hydrogen bonding present due to which is not capable of loosing its proton(H)...

6 years ago
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