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what are exceptions FRIEDAL CRAFT'S ALKYLATION?
Dear mridul,
Friedel-Crafts alkylation of methylbenzene (toluene) Where the incoming alkyl group ends up depends to a large extent on the temperature of the reaction. At 0°C, substituting methyl groups into methylbenzene, you get a mixture of the 2-.3- and 4- isomers in the proportion 54% / 17% / 29%. That's a higher proportion of the 3- isomer than you might expect. At 25°C, the proportions change to 3% / 69% / 28%. In other words the proportion of the 3- isomer has increased even more. We are all IITians and here to help you in your IIT JEE preparation. All the best. If you like this answer please approve it.... win exciting gifts by answering the questions on Discussion Forum Sagar Singh B.Tech IIT Delhi
Friedel-Crafts alkylation of methylbenzene (toluene)
Where the incoming alkyl group ends up depends to a large extent on the temperature of the reaction.
At 0°C, substituting methyl groups into methylbenzene, you get a mixture of the 2-.3- and 4- isomers in the proportion 54% / 17% / 29%. That's a higher proportion of the 3- isomer than you might expect.
At 25°C, the proportions change to 3% / 69% / 28%. In other words the proportion of the 3- isomer has increased even more.
We are all IITians and here to help you in your IIT JEE preparation. All the best. If you like this answer please approve it.... win exciting gifts by answering the questions on Discussion Forum Sagar Singh B.Tech IIT Delhi
We are all IITians and here to help you in your IIT JEE preparation. All the best.
If you like this answer please approve it....
win exciting gifts by answering the questions on Discussion Forum
Sagar Singh
B.Tech IIT Delhi
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