Question icon
Grade 12Physical Chemistry

Would you expect the second electron gain enthalpy of O as positive, more negative or less negative than the first? Justify your answer

Profile image of sudhanshu
12 Years agoGrade 12
Answers icon

4 Answers

Profile image of Gaurav
11 Years ago
Hello Student
Electronic configuration of O is 1s2, 2s2, 2p4
First electron is to be removed from 2p4 orbital. Th e2nd electron is to be removed from extra stable half filled 2p3 orbital it would require extra energy. Hence 2nd ionization energy is more positive than first one
Profile image of Ayu
9 Years ago
Due to the repulsive force from the uninegetive atom which is formed after removal of first electron hence it needs energy for it hence second electron gain enthalpy is positive.
Profile image of Rajan Sharma
8 Years ago
We are taking about electron gain enthalpy and NOT the ionization energy (as the two esteemed chemists have reported here). The first electron gain enthalpy will be negative as O both neutral and looking for electrons to complete its octet (2s2 2p4). Once it accepts an electron and becomes O-; then the next electron will only be accepted by this ion if this electron is bombarded with energy, hence the second electron gain enthalpy will be positive.
Profile image of mehar
7 Years ago
Electronic configuration of O is 1s2, 2s2, 2p4First electron is to be removed from 2p4 orbital. Th e2nd electron is to be removed from extra stable half filled 2p3 orbital it would require extra energy. Hence 2nd ionization energy is more positive than first one