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Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?

shalini , 11 Years ago
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Gaurav

Last Activity: 10 Years ago

Hello Student
The Standard free energy of formation of Cu2S is greater than those of CS2 & H2S .Hence , niether carbon nor hydrogen can reduce Cu2S to Cu metal.
On the other hand , standard free energy of formation of Cu2O is much lower than that of CO2 & hence , carbon can easily reduce Cu2O to Cu.
Cu2O+C (s) → Cu(s) +CO(g)

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