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Grade upto college level Physical Chemistry

Why coal does not burn by itself in air but once initiated by flame, it continues to burn?

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12 Years agoGrade upto college level
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ApprovedApproved Tutor Answer1 Year ago

Coal is an interesting material when it comes to combustion. At first glance, it might seem like it should ignite easily in air, but it actually requires a bit of help to get started. Let’s break down why coal doesn’t burn on its own but continues to do so once it’s ignited.

The Basics of Combustion

Combustion is a chemical reaction that occurs when a substance reacts with oxygen, producing heat and light. For a material to burn, it needs to reach a certain temperature, known as the ignition temperature. Coal, primarily composed of carbon, has a relatively high ignition temperature compared to other fuels.

Why Coal Needs an Initial Flame

When coal is exposed to air, it doesn’t ignite spontaneously for a few reasons:

  • High Ignition Temperature: Coal requires a significant amount of heat to reach its ignition point. This temperature is higher than that of many other materials, which means it won’t catch fire just from being in the presence of oxygen.
  • Surface Area: Coal often comes in large chunks, which limits the surface area available for oxygen to react with. A smaller particle size would allow for more efficient combustion, but larger pieces resist ignition.
  • Moisture Content: Coal can contain moisture, which needs to evaporate before the coal can ignite. This adds to the energy requirement for combustion.

Once Ignited, Why Does It Keep Burning?

Once coal is ignited by a flame, it enters a self-sustaining combustion phase. Here’s why:

  • Heat Generation: The initial flame provides enough heat to raise the temperature of the coal to its ignition point. As it burns, the reaction generates additional heat, which keeps the coal burning.
  • Continuous Oxygen Supply: As long as there is a sufficient supply of oxygen, the combustion reaction can continue. The heat produced helps to break down the coal further, allowing it to react with oxygen more efficiently.
  • Carbon Dioxide and Other Gases: The burning of coal produces gases like carbon dioxide and water vapor, which can help maintain the temperature needed for continued combustion.

Real-World Analogy

Think of coal like a campfire. You can’t just throw a log on the ground and expect it to catch fire. You need kindling and a flame to get it started. Once the fire is going, the logs burn steadily because they are hot enough to sustain the reaction. Similarly, coal needs that initial spark to ignite, but once it’s burning, it generates enough heat to keep the process going.

In Summary

Coal does not burn by itself in air due to its high ignition temperature, limited surface area, and moisture content. However, once it is ignited, the heat generated from the combustion reaction allows it to continue burning as long as there is a supply of oxygen. Understanding these principles helps us appreciate the complexities of combustion and the characteristics of different fuels.