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Why are free radicals so reactive?

Why are free radicals so reactive?

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sumit kumar
askIITians Faculty 13 Points
9 years ago
A free radical is a species which has one or more unpaired electrons. In the species where all electrons are paired the total magnetic moment is zero. In radicals, however, since there are one or more unpaired electrons, there is a net magnetic moment and the radicals as a result are paramagnetic. Free radicals are usually detected by electron spin resonance, which is also termed electron paramagnetic resonance.Simple alkyl radicals have a planar (trigonal) structure, i.e., these have sp2bonding with the odd electron in a p orbital. The pyramidal structure is another possibility when the bonding may be sp3and the odd electron is in an sp3orbital. The planar structure is in keeping with loss of activity when a free radical is generated at a chiral center. Thus, a planar radical will be attacked at either face after its formation with equal probability to give enantiomers. Unlike carbocations, the free radicals can be generated at bridgehead shows that pyramidal geometry for radicals is also possible and that free radicals need to be planar.
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As in the case of carbocation, the stability of free radicals is tertiary > secondary > primary and is explained on the basis of hyperconjugation. The stabilizing effects in allylic radicals and benzyl radicals is due to vinyl and phenyl groups in terms of resonance structures. Bond dissociation energies shown that 19 kcal / mol less energy is needed to form the benzyl radical from toluene than the formation of methyl radical from methane. The triphenyl methyl type radicals are no doubt stabilized by resonance, however, the major cause of their stability is the steric hindrance to dimerization.
Thanks & Regards
Sumit Kumar
askIItians Faculty

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