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Grade 11Physical Chemistry

what should be the frequency of incident light such that photoelectrons produced twice the kinetic energy if those produced by radiation of frequency 10^15 sec^-1

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8 Years agoGrade 11
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ApprovedApproved Tutor Answer1 Year ago

To determine the frequency of incident light that would produce photoelectrons with twice the kinetic energy compared to those produced by radiation of frequency \(10^{15} \, \text{s}^{-1}\), we can use the photoelectric effect equation. This equation relates the energy of the incident photons to the kinetic energy of the emitted photoelectrons.

The Photoelectric Effect Equation

The energy of a photon can be expressed using the formula:

E = hν

where:

  • E is the energy of the photon.
  • h is Planck's constant (\(6.626 \times 10^{-34} \, \text{Js}\)).
  • ν is the frequency of the incident light.

Kinetic Energy of Photoelectrons

The kinetic energy (KE) of the emitted photoelectrons is given by:

KE = E - φ

where φ (phi) is the work function of the material, which is the minimum energy required to remove an electron from the surface of the material.

Calculating the Kinetic Energy

For the initial frequency \(ν_1 = 10^{15} \, \text{s}^{-1}\), the energy of the photons is:

E_1 = hν_1 = h \cdot 10^{15}

The kinetic energy of the photoelectrons produced by this radiation is:

KE_1 = E_1 - φ = h \cdot 10^{15} - φ

Finding the New Frequency

We want to find a new frequency \(ν_2\) such that the kinetic energy of the photoelectrons produced is twice that of \(KE_1\):

KE_2 = 2KE_1

Substituting the expression for kinetic energy, we have:

KE_2 = E_2 - φ = hν_2 - φ

Setting this equal to twice the original kinetic energy gives us:

hν_2 - φ = 2(h \cdot 10^{15} - φ)

Solving for the New Frequency

Expanding the equation:

hν_2 - φ = 2h \cdot 10^{15} - 2φ

Rearranging terms leads to:

hν_2 = 2h \cdot 10^{15} - φ

Now, we can isolate \(ν_2\):

ν_2 = 2 \cdot 10^{15} - \frac{φ}{h}

Conclusion on Frequency

To find the exact value of \(ν_2\), we need to know the work function \(φ\) of the material. However, we can conclude that the new frequency \(ν_2\) must be greater than \(2 \cdot 10^{15} \, \text{s}^{-1}\) minus a small term depending on the work function. Thus, the frequency of the incident light must be sufficiently high to ensure that the kinetic energy of the emitted photoelectrons is double that of those emitted by the initial frequency of \(10^{15} \, \text{s}^{-1}\).