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Grade 12Physical Chemistry

What is the co-ordination number of calcium ion and fluoride ion in calcium fluoride respectively? CaF2

Profile image of Amrita Bhogayata
11 Years agoGrade 12
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3 Answers

Profile image of Avinash
11 Years ago
Simple ionic structures are described by two coordination numbers, one for each type of ion. Calcium fluoride (CaF2) is an (8, 4) structure, meaning that each cation Ca2+ is surrounded by eight F− anion neighbors, and each anion F− by four Ca2+.
So coordination number of Ca+2 and F- ion in CaF2 crystal are 8 and 4 resp.
Profile image of Krish Gupta
6 Years ago
CaF2 crystal are 8 and 4 resp.type structure questions are one such topic wherein not much is focussed.Simple ionic structures are described by two coordination numbers, one for each type of ion. Calcium fluoride (CaF2) is an (8, 4) structure, meaning that each cation Ca2+ is surrounded by eight F− anion neighbors, and each anion F− by four Ca2+.So coordination number of Ca+2 and F- ion in Hi, this is a good question beacuse AB
Profile image of Yash Chourasiya
6 Years ago
Dear Student

The Ca2+and Fare located in CaF2​ crystal respectively at face-centred cubic lattice points and in tetrahedral voids.
It is 8:4 arrangement, the coordination number of Ca2+and Fions is 8 and 4 ions respectively.

I hope this answer will help you.
Thanks & Regards
Yash Chourasiya