Flag Physical Chemistry> the equilibrium constant for this reversi...
question mark

the equilibrium constant for this reversible reaction is 3.6*10-7
OCl-(aq)+ H2O gives u HOCl(aq) + OH-(aq)
what is Ka for HOCl?

tanu , 9 Years ago
Grade 12th pass
anser 1 Answers
Rituraj Tiwari

We are given the equilibrium constant for the reaction:

OCl⁻(aq) + H₂O ⇌ HOCl(aq) + OH⁻(aq)
K = 3.6 × 10⁻⁷

We need to determine the acid dissociation constant (Ka) for HOCl.

Step 1: Identify the relationship between Ka and Kb
The reaction given represents the hydrolysis of the hypochlorite ion (OCl⁻), which is the conjugate base of hypochlorous acid (HOCl). The base dissociation constant (Kb) for OCl⁻ is related to the acid dissociation constant (Ka) of HOCl through the equation:

Ka × Kb = Kw

where Kw is the ionization constant of water, which is:

Kw = 1.0 × 10⁻¹⁴ at 25°C.

Since the given equilibrium constant (K) represents Kb for OCl⁻, we substitute:

Ka × (3.6 × 10⁻⁷) = 1.0 × 10⁻¹⁴

Step 2: Solve for Ka
Ka = (1.0 × 10⁻¹⁴) / (3.6 × 10⁻⁷)
Ka = 2.78 × 10⁻⁸

Final Answer:
The acid dissociation constant (Ka) for HOCl is 2.78 × 10⁻⁸.

Last Activity: 5 Years ago
star
LIVE ONLINE CLASSES

Prepraring for the competition made easy just by live online class.

tv

Full Live Access

material

Study Material

removal

Live Doubts Solving

assignment

Daily Class Assignments