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Grade 11Physical Chemistry

The average molar mass of vapor of solid ammonium chloride is nearly 26.75 g per mol . find out the vapor consists in mole fraction .

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10 Years agoGrade 11
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ApprovedApproved Tutor Answer1 Year ago

To determine the mole fraction of the vapor of solid ammonium chloride (NH4Cl) given its average molar mass of approximately 26.75 g/mol, we first need to understand what mole fraction means and how to calculate it in this context.

Understanding Mole Fraction

Mole fraction is a way of expressing the concentration of a component in a mixture. It is defined as the ratio of the number of moles of a particular component to the total number of moles of all components in the mixture. The formula for calculating mole fraction (X) is:

  • XA = nA / (nA + nB + ... + nN)

Where:

  • XA = mole fraction of component A
  • nA = number of moles of component A
  • nB, ..., nN = number of moles of other components

Calculating the Mole Fraction of Ammonium Chloride Vapor

In this case, we are focusing on the vapor of solid ammonium chloride. To find the mole fraction of the vapor, we need to know the number of moles of NH4Cl vapor and the total number of moles in the system, which may include other gases if present. However, if we assume that the vapor consists solely of NH4Cl, the calculation simplifies significantly.

Steps to Calculate the Mole Fraction

1. **Determine the number of moles of NH4Cl vapor**: If we have a certain mass of NH4Cl, we can calculate the number of moles using the formula:

  • n = mass (g) / molar mass (g/mol)

2. **Assuming pure vapor**: If the vapor consists only of NH4Cl, then the total number of moles in the system is simply the number of moles of NH4Cl. Therefore, the mole fraction of NH4Cl vapor (XNH4Cl) would be:

  • XNH4Cl = nNH4Cl / nNH4Cl = 1

Example Calculation

Let’s say we have 10 grams of NH4Cl. To find the number of moles:

  • nNH4Cl = 10 g / 26.75 g/mol ≈ 0.373 moles

Since we are assuming the vapor is pure NH4Cl, the mole fraction of NH4Cl in the vapor is:

  • XNH4Cl = 0.373 / 0.373 = 1

Final Thoughts

In a scenario where the vapor consists solely of ammonium chloride, the mole fraction of the vapor is 1, indicating that it is 100% NH4Cl. If there were other components present, you would need to account for their moles to find the mole fraction accurately. This concept is crucial in understanding gas mixtures and their behaviors in various chemical processes.