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Q.18 A solution containing 3.24 of a nonvolatile nonelectrolyte and 200 g of water boils at 100.130°C at1atm. What is the molecular weight of the solute? (Kb for water 0.513°C/m)

Sanketbhole , 6 Years ago
Grade 12
anser 1 Answers
Arun

Last Activity: 6 Years ago

We know Tb° of pure water at 1 atm is 100°C and Tb is given100.130 °C so we can calculate ΔTb by using equation 1. Then by using equation 2 we can calculate m and then we can find out the molecular weight of solute or we can directly calculate it by using equation 4.
ΔTb = Tb - Tb°
ΔTb = 100.130 °C - 100 °C  = 0.130 °C
ΔT= Kb × m   
m = 0.130 °C / 0.513°Cm-1 = 0.253 mol Kg-1
Molality m  =    w× 1000  
                M2 × w1
M2 =    w× 1000  
 m × w1
 
M2 =    3.24g × 1000  
            0.253 mol Kg-1 × 200
 
M2 = 64.03 g/mol

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