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Grade Upto college level Physical Chemistry

Name the reagents for the following I. Oxidation of primary alcohol to aldehyde. II. Oxidation of primary alcohol to carboxylic acid. III. Dehydration of prapan-2-ol to propene. IV. Reduction of butan-2-one to butan-2-ol

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12 Years agoGrade Upto college level
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ApprovedApproved Tutor Answer1 Year ago

Let's break down the reagents needed for each of the reactions you've mentioned. Each of these transformations is fundamental in organic chemistry, and knowing the right reagents is crucial for successful reactions.

Oxidation of Primary Alcohol to Aldehyde

To oxidize a primary alcohol to an aldehyde, you can use Pyridinium Chlorochromate (PCC). This reagent is particularly useful because it selectively oxidizes primary alcohols without further oxidizing the aldehyde to a carboxylic acid. Another option is Chromic Acid (H2CrO4), but this can lead to over-oxidation.

Oxidation of Primary Alcohol to Carboxylic Acid

For the oxidation of a primary alcohol to a carboxylic acid, Potassium Permanganate (KMnO4) or Chromic Acid (H2CrO4) can be used. Both of these reagents are strong oxidizers and will fully oxidize the alcohol to the carboxylic acid. KMnO4 is often used in an alkaline medium, while chromic acid is typically used in acidic conditions.

Dehydration of Propan-2-ol to Propene

The dehydration of propan-2-ol (isopropanol) to form propene can be achieved using Concentrated Sulfuric Acid (H2SO4) or Phosphoric Acid (H3PO4). These acids act as catalysts, promoting the elimination of water from the alcohol, resulting in the formation of the alkene.

Reduction of Butan-2-one to Butan-2-ol

To reduce butan-2-one to butan-2-ol, you can use Lithium Aluminium Hydride (LiAlH4) or Sodium Borohydride (NaBH4). Both of these reagents are effective reducing agents. LiAlH4 is more powerful and can reduce a wider range of carbonyl compounds, while NaBH4 is milder and often preferred for ketones due to its selectivity and safety.

Summary of Reagents

  • Primary Alcohol to Aldehyde: Pyridinium Chlorochromate (PCC) or Chromic Acid (H2CrO4)
  • Primary Alcohol to Carboxylic Acid: Potassium Permanganate (KMnO4) or Chromic Acid (H2CrO4)
  • Propan-2-ol to Propene: Concentrated Sulfuric Acid (H2SO4) or Phosphoric Acid (H3PO4)
  • Butan-2-one to Butan-2-ol: Lithium Aluminium Hydride (LiAlH4) or Sodium Borohydride (NaBH4)

Understanding these reagents and their specific applications will greatly enhance your ability to manipulate organic compounds in the lab. Each reagent has its own strengths and limitations, so choosing the right one is key to achieving the desired transformation efficiently.