Flag Physical Chemistry> in given attachment please explain why eq...
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in given attachment please explain why equivalent mass of sulfuric acid in lead storage battery is 98.

Aman , 7 Years ago
Grade 12th pass
anser 1 Answers
Arun
 
The ionic reactions of the given reaction are
PbO+ SO4-2+ 4H+ + 2e-= PbSO+ 2H2O
Pb + SO42- = PbSO4+ 2e
therefore the net reaction becomes
Pb + PbO2+ 2 h2SO4= 2PbSO+ 2H2O
here when two moles of H2SO4 are involved 2 moles of electrons are involved in the reaction.
Hence when 1 mole of sulfuric acid is involved 1 mole of electrons are involved in the rxn
Therefore n-factor for H2SO4 = 1
Last Activity: 7 Years ago
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