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Grade 12Physical Chemistry

In a body centered cubic lattice of atom the number of tetrahedral voids completely inside the unit cell is?

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8 Years agoGrade 12
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ApprovedApproved Tutor Answer1 Year ago

In a body-centered cubic (BCC) lattice, understanding the arrangement of atoms and the voids they create is crucial for grasping the material's properties. Specifically, when we talk about tetrahedral voids, we need to consider how these voids are formed within the structure of the unit cell.

Understanding the BCC Structure

A body-centered cubic lattice consists of atoms located at each corner of a cube and a single atom positioned at the center of the cube. This arrangement leads to a specific number of atoms per unit cell and a unique geometric configuration.

Atoms in a BCC Unit Cell

In a BCC unit cell, there are a total of 2 atoms. Each corner atom contributes 1/8 of an atom to the unit cell (since each corner is shared by eight neighboring unit cells), and the center atom contributes a full atom. Therefore, the total number of atoms is:

  • 8 corners × 1/8 = 1 atom
  • 1 center atom = 1 atom

So, 1 + 1 = 2 atoms per unit cell.

Tetrahedral Voids in BCC

Tetrahedral voids are formed when four atoms are positioned at the corners of a tetrahedron. In a BCC lattice, the arrangement allows for the formation of tetrahedral voids, but it's essential to determine how many of these voids are present within the unit cell.

Counting Tetrahedral Voids

In a BCC structure, there are a total of 12 tetrahedral voids. However, when we focus on the voids that are completely inside the unit cell, we find that there are only 2 tetrahedral voids that meet this criterion. This is because some of the tetrahedral voids are located at the edges or corners of the unit cell and are shared with adjacent cells.

Visualizing the Tetrahedral Voids

To visualize this, imagine placing a smaller sphere in the void created by the arrangement of the four atoms forming a tetrahedron. In the BCC structure, the two tetrahedral voids that are entirely contained within the unit cell are positioned in such a way that they do not overlap with any neighboring unit cells.

Summary of Key Points

  • A BCC unit cell contains 2 atoms.
  • There are 12 tetrahedral voids in total, but only 2 are completely inside the unit cell.
  • These voids are crucial for understanding the packing efficiency and properties of materials with a BCC structure.

In summary, while the BCC lattice has a rich structure with various voids, only 2 tetrahedral voids are completely contained within the unit cell. This knowledge is essential for applications in materials science, particularly when considering how atoms and voids influence the properties of metals and alloys.