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Grade 12th passPhysical Chemistry

If the potential energy of hydrogen electron is -3.02 eV then in which of the following excited level is electron present:
  1. 1st
  2. 2nd
  3. 3rd
  4. 4th

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8 Years agoGrade 12th pass
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ApprovedApproved Tutor Answer1 Year ago

To determine the excited level of a hydrogen electron based on its potential energy of -3.02 eV, we need to understand how the energy levels of hydrogen are structured. The energy levels of a hydrogen atom can be calculated using the formula:

Energy Level Formula

The energy of an electron in a hydrogen atom is given by the formula:

E_n = -13.6 eV / n²

Here, E_n is the energy of the electron at level n, and n is the principal quantum number, which can take positive integer values (1, 2, 3, ...).

Calculating Energy Levels

Let’s calculate the energy for the first four energy levels:

  • For n = 1: E₁ = -13.6 eV / 1² = -13.6 eV
  • For n = 2: E₂ = -13.6 eV / 2² = -3.4 eV
  • For n = 3: E₃ = -13.6 eV / 3² = -1.51 eV
  • For n = 4: E₄ = -13.6 eV / 4² = -0.85 eV

Identifying the Excited State

Now, we compare the given potential energy of -3.02 eV with the calculated energy levels:

  • E₁ = -13.6 eV
  • E₂ = -3.4 eV
  • E₃ = -1.51 eV
  • E₄ = -0.85 eV

The potential energy of -3.02 eV falls between the energy levels of E₂ (-3.4 eV) and E₃ (-1.51 eV). Since -3.02 eV is closer to -3.4 eV, it indicates that the electron is in the second excited state, which corresponds to the principal quantum number n = 2.

Conclusion

Thus, the electron with a potential energy of -3.02 eV is present in the 2nd energy level of the hydrogen atom. This understanding of energy levels is crucial in quantum mechanics and helps explain the behavior of electrons in atoms.