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Grade 11Physical Chemistry

How will you convert: (i) Ethanoic acid into methanamine (ii) Hexanenitrile into 1-aminopentane (iii) Methanol to ethanoic acid (iv) Ethanamine into methanamine (v) Ethanoic acid into propanoic acid (vi) Methanamine into ethanamine (vii) Nitromethane into dimethylamine (viii) Propanoic acid into ethanoic acid?

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12 Years agoGrade 11
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1 Answer

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ApprovedApproved Tutor Answer11 Months ago

To convert various organic compounds through chemical reactions, we can utilize specific reagents and reaction conditions tailored to achieve the desired transformations. Let's break down each conversion step-by-step, focusing on the mechanisms and reagents involved.

Conversion Processes

1. Ethanoic Acid to Methanamine

To convert ethanoic acid (acetic acid) to methanamine, we can use a two-step process. First, we can convert ethanoic acid to an amide by reacting it with ammonia:

  • **Step 1:** Ethanoic acid + Ammonia → Acetamide
  • **Step 2:** Acetamide can then be reduced to methanamine using a reducing agent like lithium aluminum hydride (LiAlH4).

2. Hexanenitrile to 1-Aminopentane

Hexanenitrile can be converted to 1-aminopentane through hydrolysis followed by reduction:

  • **Step 1:** Hydrolyze hexanenitrile with water and an acid (like HCl) to form hexanoic acid.
  • **Step 2:** Reduce hexanoic acid to 1-aminopentane using lithium aluminum hydride.

3. Methanol to Ethanoic Acid

The conversion of methanol to ethanoic acid can be achieved through oxidation:

  • **Step:** Methanol can be oxidized using an oxidizing agent such as potassium dichromate (K2Cr2O7) in acidic conditions to produce ethanoic acid.

4. Ethanamine to Methanamine

To convert ethanamine to methanamine, we can use a process called reductive amination:

  • **Step:** Ethanamine can be reacted with formaldehyde in the presence of a reducing agent like sodium cyanoborohydride (NaBH3CN) to yield methanamine.

5. Ethanoic Acid to Propanoic Acid

Converting ethanoic acid to propanoic acid involves a carbon chain elongation:

  • **Step:** Ethanoic acid can be reacted with a reagent like sodium cyanide (NaCN) to form propanoic acid through a process called nucleophilic substitution.

6. Methanamine to Ethanamine

The conversion of methanamine to ethanamine can be accomplished through a similar reductive amination process:

  • **Step:** React methanamine with formaldehyde and a reducing agent like NaBH3CN to produce ethanamine.

7. Nitromethane to Dimethylamine

To convert nitromethane to dimethylamine, we can use a reduction reaction:

  • **Step:** Reduce nitromethane using lithium aluminum hydride or catalytic hydrogenation to yield dimethylamine.

8. Propanoic Acid to Ethanoic Acid

To convert propanoic acid to ethanoic acid, we can utilize a decarboxylation reaction:

  • **Step:** Propanoic acid can be treated with soda lime (a mixture of NaOH and CaO) to remove a carbon dioxide molecule, resulting in ethanoic acid.

Summary of Reagents and Mechanisms

In summary, each conversion involves specific reagents and reaction conditions that facilitate the transformation of one compound into another. Understanding the underlying mechanisms, such as oxidation, reduction, and nucleophilic substitution, is crucial for mastering organic synthesis. Each step can be optimized based on the desired yield and purity of the final product.