Question icon
Grade Select GradePhysical Chemistry

How many atoms do mercury vapour molecules consisit of if the density of mercury vapour relative to air is 6.92?(Hg=200).The average mass of air is 29g/mole.

Profile image of Gautam Singh
11 Years agoGrade Select Grade
Answers icon

1 Answer

Profile image of Askiitians Tutor Team
ApprovedApproved Tutor Answer0 Years ago

To determine how many atoms are in mercury vapor molecules, we first need to understand the relationship between the density of the vapor, its molecular weight, and the molecular composition of mercury. Given that the density of mercury vapor relative to air is 6.92, we can use this information along with the molecular weights of mercury and air to find the number of atoms in a molecule of mercury vapor.

Understanding Molecular Weight and Density

The density of a gas can be expressed in terms of its molecular weight and the density of air. The formula for the density of a gas is:

Density = (Molecular Weight / Molar Volume)

In this case, we know the density of mercury vapor relative to air, which is 6.92. The average molecular weight of air is 29 g/mol, and the molecular weight of mercury (Hg) is 200 g/mol.

Calculating the Density of Mercury Vapor

To find the density of mercury vapor, we can set up the following equation based on the relative density:

Density of Hg vapor = 6.92 × Density of air

Assuming the density of air at standard conditions is approximately 1.29 g/L, we can calculate:

Density of Hg vapor = 6.92 × 1.29 g/L ≈ 8.92 g/L

Finding the Molar Mass of Mercury Vapor

Next, we can use the density of mercury vapor to find its molar mass. The molar volume of an ideal gas at standard temperature and pressure (STP) is approximately 22.4 L/mol. Using the density we calculated:

Molar Mass = Density × Molar Volume

Substituting the values we have:

Molar Mass of Hg vapor = 8.92 g/L × 22.4 L/mol ≈ 199.6 g/mol

Determining the Composition of Mercury Vapor

Since the molar mass of mercury vapor is approximately 200 g/mol, which matches the atomic weight of mercury, we can conclude that mercury vapor consists of diatomic molecules (Hg₂). This means that each molecule of mercury vapor is made up of two mercury atoms.

Final Calculation of Atoms

Thus, if we consider the molecular composition of mercury vapor, we find:

  • Each molecule of mercury vapor (Hg₂) consists of 2 mercury atoms.

In summary, the density of mercury vapor relative to air allows us to calculate its molar mass, which confirms that mercury vapor is composed of diatomic molecules. Therefore, each molecule of mercury vapor consists of 2 atoms of mercury.