give me an info for iitjee Physical Chemistry

Physical Chemistry is the branch of chemistry which is quite like mathematics and physics in
developing underlying principles of chemistry. It observes and explains the physical and
chemical properties of matter. Physical chemistry at IIT JEE level starts from basics of mole
concept, quantities at atomic level and covers energy, thermodynamics and kinetics which
forms the basis of how reactions occur. Various topics covered in physical chemistry such as
stoichiometry, chemical equilibrium, concentration of solutions, atomic structure,
thermodynamics or chemical energetic form the backbone of chemistry at IIT JEE level and
higher chemistry at graduate and post graduate level.
Physical chemistry has at least 30-40% weight-age in the IIT JEE chemistry paper and hence it is
most important of the trio – physical, organic and inorganic chemistry.

thanx  please  give me detail about atomic structure 

Atomic Structure
Fundamental Practicles
Atoms are made up-essentially, of three fundamental particles, which differ in mass and electric
charge as follows:
Electron Proton Neutron
Symbol e or e- p n
Approximate relative
mass
1/1836 1 1
Approximate relative
charge
-1 +1 0
Mass in kg 9.109534 X 10-31 1.6726485 X 10-27 1.6749543 X 10-27
Mass in amu 5.4858026 X 10-4 1.007276471 1.008665012
Actual charge/C 1.6021892 X10-19 1.6021892 X 10-19 0
The atomic mass unit (amu) is 1/12th of the mass of an individual atom of 6C12, i.e.
1.660565 ´ 10-27 kg. The neutron and proton have approximately equal masses of 1 amu and the
electron is about 1836 times lighter; its mass can sometimes be neglected as an approximation.
The electron and proton have equal, but opposite, electric charges; the neutron is not charged.
The existence of electrons in atoms was first suggested, by J.J. Thomson, as a result of
experimental work on the conduction of electricity through gases at low pressures, which
produces cathode rays and x-rays, and a study of radioactivity by Becquerel, the Curies and
Rutherford.
An atom is electrically neutral, and if it contains negatively charged electrons it must also
contain some positively charged particles, and the supposition that they existed within atoms
came about as a result of Rutherford's experiments in which he bombarded elements with
the α - rays and α-rays were given off by radioactive elements. The neutron was discovered in
1932 by James Chadwick by bombarding beryllium with α rays.
DISCOVERY OF ELECTRON:
CATHODE RAYS

During the latter half of the nineteenth century, it was found that while normally dry gases do
not conduct an electric current, they do so under very low pressure and then patches of light
are seen. The passage of electricity through gases as studied by a number of physicists,
particularly by Faraday, Davy, Crookes and J.J. Thomson.

When a current of high voltage (10,000 volts) is passed through a gas of air kept at a very low
pressure (0.01 – 0.03 mm) blue rays are seen emerging from the case. These rays are called
“Cathode Rays”.
Some of the important properties of the cathode rays studied by Sir J.J. Thomson and others
are given below:
 Cathode rays come out at right angles to the surface of the cathode and move in straight lines.
 Their path is independent on the position of the anode.
 They produce phosphorescence on certain salts like ZnS and fluorescence on glass.
 They blacken photographic plates.
 The rays pass through thin sheet of metals. If the metal sheet is too thick to be penetrated the
rays cast a shadow.
 They produce X-ray when they strike a metal.
 The rays ionize a gas through which they pass.
 They heat a substance on which they fall.
 They rotate a light wheel placed in their paths. This shows that cathode rays contain material
particles having both mass and velocity.
 The mass of a particle present in cathode rays is found to be 1/1837 of H-atom. This shows
that the particle is of sub-atomic nature.
 Cathode rays are deflected by a magnetic or an electric field showing the particle to be
electrically charged, the direction of deflection shows that they are negatively charged.
 Cathode rays contain the smallest unit of negative charge.
 No cathode ray was produced when the tube was completely evacuated.
 Different gases produce same cathode rays as they have the same e/m (charge/mass) ratio.
This indicates that the particles present in cathode rays are fundamental constituent of all
matter.
Sir J.J. Thomson named these negatively charged sub-atomic particles as electron.
“A sub-atomic particle which is a fundamental constituent of all matter having a mass
1/1837th of a H-atom and which carries the smallest unit of negative charge is called an
electron”.

Determination of Velocity and Charge/mass (e/m) ratio of Electrons:
Sir J.J. Thomson (1897) extended the cathode ray experiment for the determination of velocity
of electrons and their charge/mass ratio, The value of e/m for an electron = 1.76 x 108 C/g. For
the H+ ion (proton),
e/m = 96500/1.008 C/g.
Millikan’s Oil Drop Method: Determination of Charge on an Electron:
In 1909, Millikan measured the charge on an electron by his oil drop method. In this method a
spray of oil droplets is produced by an atomizer, some of which pass through an opening into a
viewing chamber, where we can observe them with a microscope. Often these droplets have an
electric charge, which is picked up from the friction forming the oil droplets. A droplet may
have one or more additional electrons in it, giving it a negative charge.
As the droplet falls to the bottom of the chamber, it passes between two electrically charged
plates. The droplet can be suspended between them; we adjust the voltage in the plates so that
the electrical attraction upward just balances the force of gravity downward. We then use the
voltage needed to establish this balance to calculate the mass - to charge ratio for the droplet.
Because we already know the mass of the droplet we can find the charge on it.
Millikan's found that the charge on all droplets could be expressed as whole number multiples
of e, where the value of e is 1.602 x10-19 C. By combining e/m. ratio and 'e' we calculate mass of
the electron
Me = e / (e/m) = 1.6022 x 10-19 / 1.76 x 108
= 9.104´10-31 kg
This very small value shows that the electron is a subatomic particle. Thus charge on an
electron = 1.602 x 10–19C.
DISCOVERY OF PROTON:
POSITIVE RAYS OR CANAL RAYS
Atoms are electrically neutral. Hence after the discovery of the negatively charged constituent
(electron) of an atom, attempts were made to discover the positively charged counterpart of
electrons. By using a discharge tube containing a perforated cathode. Goldstein (1886) found
that some rays passed through these holes in a direction opposite to that of the cathode rays.These are called the positive rays or canal rays. J.J. Thomson (1910) measured their charge by
mass ratio from which he was able to deduce that these contain positive ions. Their properties
are:
 They are positively charged.
 The positive charge is either equal to or whole number multiple of the charge on an electron.
 When hydrogen gas was filled in the discharge tube the positive charge on the positive rays
was equal to the negative charge on an electron, and the mass was less than the hydrogen
atom.
 Unlike cathode rays the properties of positive rays are characteristics of the gas in the tube.
 The deflection of positive rays under the influence of an electric or magnetic field is smaller
than that of the cathode rays for the same strength of field. This shows that the positive rays
have a greater mass than that of electrons.
 The mass of the positive rays depends on the atomic weights or molecular weights of the gases
in the discharge tube. The charge/mass ratio also varies because the change in positive charge
on the rays. It may be either equal to or integral multiple of the charge on an electron.
 The lightest of all particles identified in positive rays from different elements was one with a
mass very slightly less than that of hydrogen atom (or nearly equal to H-atom). The lightest
positively charged particle is called a proton (P or P+). Positive rays are atomic or molecular
resides from which some electrons have been removed. The removed electrons constitute the
cathode rays and the positive residues form the positive or canal rays.
Positive Rays Cathode Rays
H H+ e–
O → O+ e–
O2 → O2
+ e–
O2 → O2
2+ 2e–
The mass of a proton is very slightly less than that of a H-atom. This shows that protons are subatomic
particles. Protons are fundamental constituent of matter because positive rays are
produced by all substances.
“A sub-atomic particle, which is a fundamental constituent of all matter having a mass slightly
less than that of H-atom and which carries a positive charge equal in magnitude to the charge
on an electron, is called a proton”. A proton is denoted by p or p+ of +1p.