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Grade 12th passPhysical Chemistry

Find out number of allylic and number of teritary carbon in given structure .and also find number of vinylic carbon.

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8 Years agoGrade 12th pass
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ApprovedApproved Tutor Answer1 Year ago

To determine the number of allylic, tertiary, and vinylic carbons in a given organic structure, we first need to understand what each of these terms means in the context of organic chemistry. Let’s break down each type of carbon and how to identify them in a molecular structure.

Understanding Carbon Types

Allylic Carbons

Allylic carbons are those that are adjacent to a double bond. Specifically, if you have a carbon-carbon double bond (C=C), the carbons directly next to it (one on each side) are considered allylic. For example, in the structure of propene (CH2=CH-CH3), the carbon in the middle (the one bonded to the double bond) is not allylic, but the two carbons on either side of the double bond are.

Tertiary Carbons

A tertiary carbon is one that is bonded to three other carbon atoms. This typically occurs in branched alkanes. For instance, in isobutane (C4H10), the central carbon is tertiary because it is connected to three other carbons. To identify tertiary carbons, look for carbons that have three other carbons directly attached to them.

Vinylic Carbons

Vinylic carbons are those that are part of a double bond. In a C=C bond, the carbons involved in the double bond are considered vinylic. For example, in ethylene (C2H4), both carbons are vinylic because they are part of the double bond.

Steps to Identify Each Type of Carbon

  • Examine the Structure: Start by looking at the molecular structure you have. Identify all the carbon atoms present.
  • Locate Double Bonds: Identify any double bonds in the structure. This will help you find the vinylic and allylic carbons.
  • Count Vinylic Carbons: Count the carbons that are directly involved in the double bonds.
  • Identify Allylic Carbons: For each double bond, check the carbons adjacent to it and count them as allylic.
  • Find Tertiary Carbons: Look for carbons that are bonded to three other carbons and count them as tertiary.

Example Analysis

Let’s say you have a structure like 2-methylpropene (C4H8), which has a double bond between the first and second carbon atoms:

  • Vinylic Carbons: The first and second carbons are vinylic.
  • Allylic Carbons: The third carbon is allylic because it is adjacent to the double bond.
  • Tertiary Carbons: The second carbon is tertiary since it is bonded to three other carbons (the first, third, and the methyl group).

In this example, you would have:

  • 2 vinylic carbons
  • 1 allylic carbon
  • 1 tertiary carbon

By following these steps and definitions, you can accurately identify the number of allylic, tertiary, and vinylic carbons in any given structure. If you have a specific structure in mind, feel free to share it, and we can analyze it together!