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Grade upto college level Physical Chemistry

Can a copper spoon be used to stir a solution of ZnSO 4?Support your answer with reason. Given : E ocu +2/cu = +0.34 V, E ozn +2/zn =-0.76 V

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12 Years agoGrade upto college level
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ApprovedApproved Tutor Answer1 Year ago

When considering whether a copper spoon can be used to stir a solution of zinc sulfate (ZnSO4), we need to look at the electrochemical properties of both copper and zinc. The standard reduction potentials you've provided are crucial for understanding the reactivity of these metals in solution.

Understanding Electrochemical Reactions

The standard reduction potential (E°) indicates how likely a species is to gain electrons and be reduced. A higher E° value means a greater tendency to be reduced. In this case:

  • E° Cu2+/Cu = +0.34 V: This indicates that copper ions (Cu2+) are more likely to be reduced to solid copper.
  • E° Zn2+/Zn = -0.76 V: This shows that zinc ions (Zn2+) are less likely to be reduced compared to copper.

Reactivity of Copper and Zinc

Since copper has a higher reduction potential than zinc, it means that copper is a better oxidizing agent. In simpler terms, if you place a copper spoon in a zinc sulfate solution, the copper can potentially oxidize, while the zinc ions in the solution can be reduced. This reaction can be represented as follows:

Cu (s) → Cu2+ (aq) + 2e-

Zn2+ (aq) + 2e- → Zn (s)

What Happens When Copper Contacts Zinc Sulfate?

When the copper spoon stirs the ZnSO4 solution, the following occurs:

  • The copper can dissolve into the solution as Cu2+ ions, which means the copper spoon will corrode over time.
  • Simultaneously, zinc ions in the solution can be reduced to solid zinc, potentially depositing on the spoon or in the solution.

Practical Implications

Using a copper spoon in a zinc sulfate solution is not advisable because:

  • The copper will gradually dissolve, leading to contamination of the solution with copper ions.
  • This could affect any experiments or reactions you are conducting with the ZnSO4 solution, as the presence of copper ions can alter the expected outcomes.

Conclusion

In summary, while a copper spoon can technically stir a zinc sulfate solution, it is not a good choice due to the potential for copper to dissolve into the solution and interfere with the chemistry at play. For stirring such solutions, it would be better to use a material that does not react with the components of the solution, such as glass or plastic.