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Grade 12Physical Chemistry

as we know that in case of quantum numbers
magnetic quantum number varies as -L to +L....
if l=1, can we determine to which orbital does m=0,m=1 and m=(-1) represent??
a)m=o → px , m=1 → py , m=(-1) → pz
b) m=0 → pz , m=1 → py, m=(-1) → px

Profile image of Ayush Mishra
11 Years agoGrade 12
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1 Answer

Profile image of Ramreddy
11 Years ago
Unlike the spherically symmetric s orbitals, a p orbital is oriented along a specific axis. All p orbitals have l = 1, and there are three possible values for m (-1, 0, +1). Whenever m does not equal zero, the wave function is complex (both imaginary and real), which makes visualization of the wave function difficult. Chemists generally combine the complex wave functions to create new wave functions that are real. (The Schrödinger equation for the hydrogen atom is a linear differential equation. One consequence is that any linear combination of wave functions is also a valid wave function.) For l = 1, the m = 0 wave function is designated pz. The m = -1 and +1 wave functions are combined to produce two new wave functions, which are designated px and py.