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Grade 11Physical Chemistry

A vertical hollow cylinder of height 1.52m is fitted with a movable piston of negligible mass and thickness l.the lower half of the cylinder contains an ideal gas and the upper half is filled with mercury .the cylinder is initially at 300k.when the temperature is raised half o the mercury comes out of the cylinder. Find the temperature assuming the thermal expansion of mercury to be negligible

Profile image of Akansh
6 Years agoGrade 11
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1 Answer

Profile image of Vikas TU
6 Years ago
Dear student 
Pressure of gas = pressure of Hg(mercury) + pressure of atmospheric air
Pressure of Gas = 76 cm of Hg + 76 cm of air.
Pressure of Gas P₁ = 152 cm.  Cylinder initial  (T₁) = 30  V = V₁ /2 , here V₁ is the volume of the cylinder.  V = 76/2 =38
After heating ,  Pressure of Gas = Pressure of Hg + Pressure of Atmospheric air
= 38 + 76
P₂= 114 cm.   , V₂ = 3V₁ /4
Now applying the Gas equation .    
= (152 x V₁) / 2 x 300 = [144 x (3V₁/4) ] / T₂
= (300 × 2 × 3 × 114) / 152 × 4
T₂ = 337.5