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A sample of pure PCl5 was introduced into an evacuated vessel at 473 K. After equilibrium was attained, concentration of PCl5 was found to be 0.5 × 10–1 mol L–1. If value of Kc is 8.3 × 10–3, what are the concentrations of PCl3 and Cl2 at equilibrium?

sudhanshu , 11 Years ago
Grade 12
anser 1 Answers
Gaurav

Last Activity: 10 Years ago

PCl5 -> PCl3 + Cl2
Let the concentration of PCl5 and Cl2 be x at equilibrium.
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Or 4.15 × 10-4 = x2 Or x = 2 × 10-2 = 0.02 mol L-1 Hence the concentration of PCl5 and Cl2 each at equilibrium = 0.02 mol L

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