Dear student
Hardness of effluent sample is 6/28 th of hardness of CaCl2 solution
111 parts of CaCl2 = 100 parts of CaCO3
0.136 parts (mol. wt.) of CaCl2 = 100 * 0.136 / 111 = 0.123 parts of CaCO3
Hence hardness of CaCl2 = 123 ppm
Hence hardness of effluent sample = 123 * 6 / 28 = 26 ppm
Regards
Arun (askIITians forum expert)