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As we already know that :
Cp - Cv = -T * (dS/dV)T * (dS/dP)T
For Absolute Zero : A perfect crystal at Absolute Zero (0K) has Entropy (S) = 0 and according to the equation Cp - Cv tends to Zero, That''s Why : Y = (Cp/Cv) = 1
For Triple Point : Cp - Cv not equals to zero
For Critical Point : At the critical point, gamma would be infinite.
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