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The solubility of silver chloride in 0.2 M NaCl is (Given Ksp AgCl = 1.8 × 10−10)
(A) 9 × 10−10 M
(B) 3.6 × 10−10 M
(C) 1.8 × 10−11 M
(D) 7.2 × 10−10 M
Since NaCl is a strong electrolyte therefore the entire conc. of Cl− ions comes from NaCl Ksp AgCl = [Ag+] [Cl−]. If solubility of Ag+ = s in NaCl then
(A)
NaCl dissociates fully to give [Cl-] = 0.2 and contribution of [Cl-] from AgCl is negligible compared to it.
So, Ksp = [Ag+][Cl-] = 1.8*10^(-10)
Find [Ag+] which will be the solubility.
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