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How to calculate equivalent weight in a diproportionation redox reaction? Give an example.

Anurag Kshatri , 11 Years ago
Grade 12
anser 1 Answers
Aman Bansal

Last Activity: 11 Years ago

Dear Anurag,

Equivalent weight of Oxidising and Reducing Agents


Equivalent weight of a substance (oxidant or reductant) is equal to molecular weight divided by number of electrons lost or gained by one molecule of the substance in a redox reaction.

Eq. wt. of O. A. 

                       =

Eq. wt. of R. A.  = 

                       = 

  Table : Equivalent weight of few oxidising/reducing agents
 

Agents

O. N.

Product

O. N.

Change in
O. N. per
atom

Total 
Change in
O. N. per  mole

Eq. wt.

+ 6

+ 3

3

3 × 2 = 6

Mol. wt./6

+ 3

+ 4

1

1 × 2 = 2

Mol. wt./2

+ 2

+ 2.5

0.5

0.5 × 2 = 1

Mol. wt./1

– 1

– 2

1

1 × 2 = 2

Mol. wt./2

– 1

0

1

1 × 2 = 2

Mol. wt./2


(Acidic medium)

+ 7

+ 2

5

5 × 1 = 5

Mol. wt./5


(Neutral medium)

+ 7

+ 4

3

3 × 1 = 3

Mol. wt./3


(Alkaline medium)

+ 7

+ 6

1

1 × 1 = 1

Mol. wt./1


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