askiitian.expert- chandra sekhar
Last Activity: 15 Years ago
Hi Ankur,
[Pb+2] [S2-] = Ksp = 3.4 * 10^-28
[PbS] = [Pb+2] = 0.001 (saturated)
[S2-]= 3.4 * 10^-25
Ka = 1.1 * 10^-23 = [H+]2[S-2]/[H2S]
[H+]2 = 1.1/3.4 * 10^2 * 0.1
[H+] = 1.8
since due to the very small Ka value of H2S the H+ furnished by it is negligible.
Therefore the 1.8 M HCl is to be added.