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Grade 12Physical Chemistry

116mg of a certain compound on vaporisation displaces 44.8ml of air. What is the molecular mass of the same?
The correct answer (as per my book) is 58, which is easily obtained by considering that 116mg displaces 44.8ml and hence 22400ml being displaced by 58 gram. However, if I try to use the formula: Molar Mass = 2 x Vapor Density, I get 116 gram instead. Here's how: Vap. Density = (116mg/44.8ml)/(1g/22.4L) = 58. Hence Molec. Mass = 58 x 2 = 116. Where am I wrong?

Profile image of tabm2
10 Years agoGrade 12
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2 Answers

Profile image of Sakshi
10 Years ago
i didnt get why u used the formula of this vapour density here
Profile image of tabm2
10 Years ago
@Sakshi That’s just another method. Anyways I figured it out. It should be 2g/22.4L instead of 1g/22.4L in the relation of VD.