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Grade 12Physical Chemistry

0.2M HCl and 0.3M H3PO3 with alpha=0.2 are mixed.what is the ph of the resulting solution??????????????????????

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9 Years agoGrade 12
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ApprovedApproved Tutor Answer1 Year ago

To find the pH of a solution formed by mixing 0.2 M HCl and 0.3 M H₃PO₃ (phosphorous acid), we need to consider the contributions of both acids to the overall acidity of the solution. HCl is a strong acid, while H₃PO₃ is a weak acid with a degree of dissociation (α) of 0.2. Let’s break this down step by step.

Step 1: Calculate the Contribution of HCl

HCl is a strong acid, meaning it completely dissociates in solution. Therefore, the concentration of hydrogen ions [H⁺] contributed by HCl is equal to its concentration:

  • [H⁺] from HCl = 0.2 M

Step 2: Calculate the Contribution of H₃PO₃

H₃PO₃ is a weak acid, and we can calculate its contribution to [H⁺] using its degree of dissociation (α). The formula for the concentration of hydrogen ions from a weak acid is:

  • [H⁺] from H₃PO₃ = C × α

Where C is the concentration of the weak acid. For H₃PO₃:

  • C = 0.3 M
  • α = 0.2

Now, substituting the values:

  • [H⁺] from H₃PO₃ = 0.3 M × 0.2 = 0.06 M

Step 3: Total [H⁺] in the Mixture

Now, we can find the total concentration of hydrogen ions in the mixed solution by adding the contributions from both acids:

  • Total [H⁺] = [H⁺] from HCl + [H⁺] from H₃PO₃
  • Total [H⁺] = 0.2 M + 0.06 M = 0.26 M

Step 4: Calculate the pH

The pH of a solution is calculated using the formula:

  • pH = -log[H⁺]

Substituting the total [H⁺] we found:

  • pH = -log(0.26)

Using a calculator, we find:

  • pH ≈ 0.586

Final Result

Thus, the pH of the resulting solution after mixing 0.2 M HCl and 0.3 M H₃PO₃ with α = 0.2 is approximately 0.59. This indicates a strongly acidic solution due to the presence of both a strong and a weak acid.