First write the Balnced eqns.
for the given compound,
CxHyClz + (2x+y/2) O2 ---------------> xCO2 + y/2H2O + z/2Cl2
0.220/(12x +y + 35.5z) 0.195/44x 0.0804/9y 0.120/n*(z/2)
these are their equ. weights.
find n .i.e moles of Cl2 from given pressure, temp, and volume by pv=nrt
And equate the eq. weight of the Molecular compound with each product and get the values of x, y and z.